Lithium-ion cell architecture, one physical layer at a time
First assemble the five physical layers. Then keep that same stack visible while zooming into a
selected layer. Solvent molecules appear only after you enter an electrolyte-filled pore.
Conceptual visualization only. Layer widths, particle sizes, pore sizes, molecular geometry, motion
and timing are not to scale and are not model outputs. Animation or transition speed does not represent
current, C-rate, conductivity, diffusivity, reaction rate, state of charge or elapsed time.
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Step 1 · Assemble the five physical layers
The cell is a strict left-to-right stack. Add one layer at a time; the next step stays unavailable
until all five are visible.
Negative side → Positive side1 of 5 layers visible
The electrolyte matters — but it is not layer 6.
The liquid electrolyte fills connected pores inside layers 2, 3 and 4. The metallic collectors are
dense solids and hold no electrolyte at all.
One more simplification worth naming: a real cell coats both faces of each collector and
repeats this sandwich many times, wound or stacked. This page shows a single repeat unit.
Step 2 · Zoom into one selected layer
The rail above shows where the zoom comes from. Choose a layer; the view and explanation change
without losing the parent stack.
Component under pointer
Move the pointer over an item to identify it.
Whole cell stack››Layer interior
Step 3 · Enter the liquid inside a selected pore
Locked until a porous layer is selected, so solvent molecules never appear without an
architectural location.
🔒Molecule view is locked
Select a porous layer in Step 2, then use Zoom into pore electrolyte.
Selects Layer 2 · Negative composite electrode and focuses the next button.
Watch ions separate and solvent molecules reorient
LiPF₆ is an ionic salt. Three stages: an associated Li⁺···PF₆⁻ pair, greater ion separation,
and a conceptual local solvent response.
What changes
What does not change
Conceptual local arrangementLi⁺PF₆⁻
OECδ+
OEMCδ+
ODMCδ+
OECδ+
δ+EMCO
δ+DMCO
δ+ECO
O oxygen-rich endδ+ more electropositive region
Step 4 · Connect transport paths back to the layers
Transport uses the same physical stack, not a new disconnected diagram.
Electronic path
Electrons move through metallic collectors, conductive solids in the electrodes, and the external
circuit. The separator blocks any direct electronic contact.
Inside collectors: electrons move through dense metal.
Inside composite electrodes: electrons move through active material and conductive-additive networks.
Across the separator: no intended electronic path.
Ionic path
Li⁺ moves through the connected liquid that fills electrode pores and separator pores.
The liquid phase is continuous through porous regions but never fills the metallic collectors.
Thermal shutdown: some polyolefin separators are designed to soften and close pores at elevated temperature, reducing ionic transport. This behavior is not universal and cannot prevent every failure mode.